Marlinda, Lenny (2022) Turnitin Artikel "Biofuel from hydrocracking of Cerbera manghas oil over Ni-Zn/HZSM-5 catalyst". Universitas Jambi. (Unpublished)
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Text (Turnitin Artikel)
Turnitin_EQJ Paper_Lenny.pdf - Accepted Version Download (7MB) |
Abstract
The effects of reaction temperature on the hydrocarbon composition of biofuel produced in hydrocracking of Cerbera manghas oil with Ni-Zn/HZSM-5 catalyst were investigated. The incipient wetness impregnation method was applied to prepare the Ni-Zn/HZSM-5 catalysts. Furthermore, the properties of catalysts were measured by X-ray diffraction, atomic absorption spectrometry, and nitrogen physisorption. Hydrocracking process was carried out in Parr USA pressure batch reactor at pressure of 20 5 bar after flowing H2 for 1 h. The reaction with a catalyst/oil ratio of 1 g/150 mL proceeded at various temperatures of 350, 375 and 400 °C for 2 h. Gas chromatography-mass spectrometry was used to analyze biofuel. The most abundant hydrocarbon compounds in biofuel were identified as pentadecane and heptadecane (a major diesel fuel compound) with a different amount at different reaction temperatures. It can be said that the hydrodecarboxylation/decarbony lation routes were the predominant reaction pathways and oxygen removal occurred during hydrocracking. The Cerbera manghas oil can be recommended as a promising biofeed to produce the gasoil as an alternative transportation fuel.
| Type: | Other |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Fakultas Sains dan Teknologi > Kimia Industri |
| Depositing User: | Marlinda |
| Date Deposited: | 05 May 2023 08:24 |
| Last Modified: | 24 May 2023 02:49 |
| URI: | https://repository.unja.ac.id/id/eprint/47657 |
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