Liebing, Phil and Husien, Asrial A. and Fischer, Axel and Nietzschmann, Eckhart and Edelmann, Frank T. (2017) Macromolecular Self-Assembly of Organotin(IV) Squarates and Croconates - Preparation and Crystal Structures of [SnMe2 (H2 O)2 ]C4 O4 , [SnMe3 ]2 C4 O4 , and [SnMe3 (H2 O)]2 C5 O5. Zeitschrift für anorganische und allgemeine Chemie, 643 (8). pp. 536-543. ISSN 00442313
Full text not available from this repository.Abstract
The new organotin(IV) squarates and croconates [SnMe2(H2O)2]C4O4 (1), [SnMe3]2C4O4 (2), and [SnMe3(H2O)]2C5O5 (3), were prepared by salt metathesis from the appropriate sodium salts, and characterized by single-crystal X-ray diffraction and infrared spectroscopy. While 1 and 2 are coordination polymers with bridging C4O42– anions, compound 3 exists as a monomer in the solid state. In the hydrated compounds 1 and 3, the molecules are interconnected by various types of O–H···O bridges between non-coordinated carbonyl oxygen atoms and water ligands, resulting in a supramolecular layer (1, 2) or network structure (3), respectively.
| Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Fakultas Keguruan dan Ilmu Pendidikan > Pendidikan Kimia |
| Depositing User: | Asrial |
| Date Deposited: | 24 May 2017 04:16 |
| Last Modified: | 24 May 2017 04:16 |
| URI: | https://repository.unja.ac.id/id/eprint/660 |
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