Asrial, Asrial and Olbrich, Falk and Spoida, Marlies and Fischer, Axel and Edelmann, Frank T. (2010) Crystal Engineering with Oxo- and Cyanocarbon Anions: Synthesis and Structural Characterization of Triorganotin(IV) Pentacyanopropenides and Hexacyanoazapentadienides. Zeitschrift für anorganische und allgemeine Chemie. n/a-n/a. ISSN 00442313
Full text not available from this repository.Abstract
The first triorganotin(IV) pentacyanopropenides, [R3Sn(H2O)2][C3(CN)5] (R = Me (2), nBu (3), Ph (4) were prepared by treatment of Ag[C3(CN)5] (1) with equimolar amounts of R3SnCl in reagent grade THF. In a similar manner, dark red [R3Sn(H2O)2][N{C(CN)C(CN)2}2] (6) containing the hexacyanoazapentadienyl anion was prepared in 55 % yield. The molecular structure of [Ph3Sn(H2O)2][C3(CN)5] (4) was determined by X-ray diffraction. The crystal structure consists of separated trigonal-bipyramidal [Ph3Sn(H2O)2]+ cations and nearly planar [C3(CN)5]– anions which are linked through O–H···N hydrogen bonds to give a three-dimensional network.
| Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Fakultas Keguruan dan Ilmu Pendidikan > Pendidikan Kimia |
| Depositing User: | Asrial |
| Date Deposited: | 24 May 2017 04:50 |
| Last Modified: | 24 May 2017 04:50 |
| URI: | https://repository.unja.ac.id/id/eprint/664 |
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